Chemistry of Heteroaromatic Compounds
Heteroaromaticity; comparison of electron rich and electron deficient heteroaromatic systems. Synthesis of pyrrole, furane, thiophen, diazoles, oxygen- and sulfur-containing azoles and their benzologues. Reactivity of five-membered heterocycles. Synthetic possibilities of the pyridine ring and its benzologues with particular respect to modern methods. Synthesis of diazines and their benzologues. Reactivity of six-membered heteroaromatics. Synthesis and reactivity of fused ring systems with bridge-head nitrogen atom. Zwitterionic ring systems: synthesis and reactivity. Ring transformation of heterocyclic compounds. Small (3- and 4-membered) and large (7-membered) ring skeletons. Nomenclature of heterocycles.
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