SUBJECT
Ring Transformations in Heterocyclic Chemistry
lecture
Master
2
Semester 2
Spring semester
Systematic discussion and mechanistic interpretation of ring transformation of heterocyclic compounds with different ring size. The discussed conversions are distributed according to the synthetic methods using elektrophilic-, nucleophilic- dienophilic and dipolarophilic reagents, metal-containing catalysts and photolytic conditions. The syntheses of parent compounds with more complicated structures are also discussed. Special emphasis is put on the structure-reactivity relationships which can be rationalized on the basis of reaction mechanism.
Suggested:
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H. C. Van der Plas: Ring Transformations of Heterocycles I-II (Academic Press, 1973)
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John A. Joule, Keith Mills: Heterocyclic Chemistry at A Glance 2th Edition WILEY, 2012, ISBN:978-0-470-97122-2.
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John A. Joule, Keith Mills: Heterocyclic Chemistry, 5th Edition WILEY, 2010 ISBN:978-1-4051-3300-5.
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Rakesh Kumar Parashar: Reaction Mechanisms in Organic Synthesis, 2008, Wiley ISBN: 978-1-4051-5072-9.